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A catalytic converter is a vehicle emission control device that converts toxic pollutants in exhaust gas to less-toxic pollutants by catalyzing a redox reaction (oxidation or reduction). A catalytic converter comprised usually of the following three main parts is used in internal combustion engines: substrate, washcoat, and catalytic materials. The substrate material is usually a ceramic monolith with a honeycomb structure. A washcoat, usually aluminum oxide, titanium dioxide, silicon dioxide, or a mixture of silica and alumina, is used as a carrier for the catalytic materials.
The catalytic converter can reduce oxides of nitrogen (NOx) into nitrogen gas (N2), combine or oxidize carbon monoxide (CO) with/or unburned hydrocarbons (HC) to produce carbon dioxide (CO2) and water (H2O). The reaction typically takes place at an optimal temperature range between 630 and 720 K, but can operate from 500 to 720 K with longer residence times. To operate an effective process, the engine requires an external urea tank and dosing system. The specific NOx/ammonia and ammonia/catalyst ratios can be designed to optimize a specific application. At optimal conditions, the application of a catalyst downstream of the engine can reduce NOx emissions from vehicles by 70–90%.
To reduce NOx, a controlled amount of the reactive chemical reductant such as anhydrous ammonia, aqueous ammonia, and urea is added to a stream of fuel or exhaust gas and adsorbed onto the catalyst.